|A drawing illustrates the unusual topological landscape around a pair of features known as exceptional points (red dots), showing the emergence of a Fermi arc (pink line at center), and exotic polarization contours that form a Mobius-strip-like texture (top and bottom strips). Courtesy of the researchers|
Topological effects, such as those found in crystals whose surfaces conduct electricity while their bulk does not, have been an exciting topic of physics research in recent years and were the subject of the 2016 Nobel Prize in physics. Now, a team of researchers at MIT and elsewhere has found novel topological phenomena in a different class of systems — open systems, where energy or material can enter or be emitted, as opposed to closed systems with no such exchange with the outside.
This could open up some new realms of basic physics research, the team says, and might ultimately lead to new kinds of lasers and other technologies.
The results are being reported in the journal Science, in a paper by recent MIT graduate Hengyun “Harry” Zhou, MIT visiting scholar Chao Peng (a professor at Peking University), MIT graduate student Yoseob Yoon, recent MIT graduates Bo Zhen and Chia Wei Hsu, MIT Professor Marin Soljačić, the Francis Wright Davis Professor of Physics John Joannopoulos, the Haslam and Dewey Professor of Chemistry Keith Nelson, and the Lawrence C. and Sarah W. Biedenharn Career Development Assistant Professor Liang Fu.
In most research in the field of topological physical effects, Soljačić says, so-called “open” systems — in physics terms, these are known as non-Hermitian systems — were not studied much in experimental work. The complexities involved in measuring or analyzing phenomena in which energy or matter can be added or lost through radiation generally make these systems more difficult to study and analyze in a controlled fashion.
But in this work, the team used a method that made these open systems accessible, and “we found interesting topological properties in these non-Hermitian systems,” Zhou says. In particular, they found two specific kinds of effects that are distinctive topological signatures of non-Hermitian systems. One of these is a kind of band feature they refer to as a bulk Fermi arc, and the other is an unusual kind of changing polarization, or orientation of light waves, emitted by the photonic crystal used for the study.
Photonic crystals are materials in which billions of very precisely shaped and oriented tiny holes are made, causing light to interact in unusual ways with the material. Such crystals have been actively studied for the exotic interactions they induce between light and matter, which hold the potential for new kinds of light-based computing systems or light-emitting devices. But while much of this research has been done using closed, Hermitian systems, most of the potential real-world applications involve open systems, so the new observations made by this team could open up whole new areas of research, the researchers say.
Fermi arcs, one of the unique phenomena the team found, defy the common intuition that energy contours are necessarily closed curves. They have been observed before in closed systems, but in those systems they always form on the two-dimensional surfaces of a three-dimensional system. In the new work, for the first time, the researchers found a Fermi arc that resides in the bulk of a system. This bulk Fermi arc connects two points in the emission directions, which are known as exceptional points — another characteristic of open topological systems.
The other phenomenon they observed consists of a field of light in which the polarization changes according to the emission direction, gradually forming a half-twist as one follows the direction along a loop and returns back to the starting point. “As you go around this crystal, the polarization of the light actually flips,” Zhou says.
This half-twist is analogous to a Möbius strip, he explains, in which a strip of paper is twisted a half-turn before connecting it to its other end, creating a band that has only one side. This Möbius-like twist in light polarization, Zhen says, could in theory lead to new ways of increasing the amount of data that could be sent through fiber-optic links.
The new work is “mostly of scientific interest, rather than technological,” Soljačić says. Zhen adds that “now we have this very interesting technique to probe the properties of non-Hermitian systems.” But there is also a possibility that the work may ultimately lead to new devices, including new kinds of lasers or light-emitting devices, they say.
The new findings were made possible by earlier research by many of the same team members, in which they found a way to use light scattered from a photonic crystal to produce direct images that reveal the energy contours of the material, rather than having to calculate those contours indirectly.
“We had a hunch” that such half-twist behavior was possible and could be “quite interesting,” Soljačić says, but actually finding it required “quite a bit of searching to figure out, how do we make it happen?”
“Perhaps the most ingenious aspect of this work is that the authors use the fact that their system must necessarily lose photons, which is usually an obstacle and annoyance, to access new topological physics,” says Mikael Rechtsman, an assistant professor of physics at Pennsylvania State University who was not involved in this work. “Without the loss … this would have required highly complex 3-D fabrication methods that likely would not have been possible.” In other words, he says, the technique they developed “gave them access to 2-D physics that would have been conventionally thought impossible.”
The work was supported by the Army Research Office through the Institute for Soldier Nanotechnologies; S3TEC, an Energy Frontier Research Center funded by the U.S. Department of Energy; the U.S. Air Force; and the National Science Foundation.
Read more at the MIT News Office.
David L. Chandler | MIT News Office
January 11, 2018
|MIT AIM Photonics Academy Executive Lionel Kimerling speaks during a meeting at Stonehill College in Easton, Mass., on Nov. 14, 2017. “With the help of the state, Massachusetts can be the Silicon Valley for the growth of ultra-high performance communications systems using integrated photonics,” Kimerling said. Photo, Rich Morgan|
MIT’s AIM Photonics Academy helped organize a gathering of more than 60 people at Stonehill College in Easton, Mass., on Nov. 14, 2017, to explore opportunities in integrated photonics, and discuss possibilities for a large investment to create a Lab for Education & Application Prototypes (LEAP) in integrated photonics at the college. Attendees came from companies, colleges and universities, the Massachusetts Manufacturing Extension Program, Massachusetts Technology Collaborative and aides to U.S. Rep. Joseph P. Kennedy III, D-Mass.
Integrated photonics uses complex optical circuits to process and transmit signals of light, similar to the routing of electrical signals in a computer microchip. In contrast to the electrical transmission in a microchip, a photonic integrated circuit can transmit multiple information channels simultaneously using different wavelengths of light with minimal interference and energy loss to enable high-bandwidth, low-power communications.
“Students need to be prepared for the jobs that are coming,” said Dr. Cheryl Schnitzer, associate professor of chemistry at Stonehill College. “It’s our obligation to teach them about the exploding field of photonics and integrated photonics.”
MIT’s AIM Photonics Academy is the education and workforce development arm of the AIM Photonics Institute, one of 14 Manufacturing USA institutes launched as part of a federal initiative to revitalize American manufacturing. The federal government has committed $110 million to the AIM Photonics Institute over five years. At the same time, the state of Massachusetts will spend $100 million on projects related to colleges and industry within the state, including $28 million to help launch AIM Photonics projects such as LEAP facilities.
|Anu Agarwal, MIT Principal Research Scientist, speaks during an AIM Photonics Academy meeting at Stonehill College in Easton, Mass., on Nov. 14, 2017. Stonehill is considering creation of a Lab for Education & Application Prototypes (LEAP) in integrated photonics at the college. Photo, Rich Morgan|
MIT received funding for the first LEAP facility, with a focus on packaging. The MIT Lab for Education & Application Prototypes is currently housed in Building 35, and will relocate to the fifth floor of MIT.nano in June 2018. A second LEAP site is in its final stages of planning at Worcester Polytechnic Institute, and it will also serve Quinsigamond Community College. AIM Photonics Academy and the Commonwealth of Massachusetts are in discussions to build four more LEAP Labs, including one at Stonehill College to serve the southeastern corner of the state. Once up and running, these labs will form a training network that helps Massachusetts become a major hub for photonics technology.
The meeting at Stonehill College, which also included the NextFlex Flexible Hybrid Electronics manufacturing innovation institute, generated many plans. The college has already connected with Bridgewater State and Bristol Community Colleges about creating photonic tracks in their programs. A team from AIM Photonics Academy, Stonehill College and MassTech will begin visiting companies to follow up on how they might get engaged in a LEAP Lab at Stonehill.
Companies were enthusiastic about the opportunity to expand in these areas, as well. “Any time you add high-tech education to an area, you are going to incubate high-tech companies,” noted John Lescinskas of Brockton Electro-Optics. “You’re planting a seed. It can lead to a tree, or even a forest.”
Massachusetts is an optimal location for this initiative to take place. Integrated photonics “is a technology that originated in Massachusetts, at MIT,” said AIM Photonics Academy Executive Lionel Kimerling. “With the help of the state, Massachusetts can be the Silicon Valley for the growth of ultra-high performance communications systems using integrated photonics,” Kimerling said.
– Julie Diop, Program Manager, AIM Photonics Academy
November 27, 2017
|Researchers have designed a light-emitter and detector that can be integrated into silicon CMOS chips. This illustration shows a molybdenum ditelluride light source for silicon photonics. Illustration, Sampson Wilcox|
The huge increase in computing performance in recent decades has been achieved by squeezing ever more transistors into a tighter space on microchips.
However, this downsizing has also meant packing the wiring within microprocessors ever more tightly together, leading to effects such as signal leakage between components, which can slow down communication between different parts of the chip. This delay, known as the “interconnect bottleneck,” is becoming an increasing problem in high-speed computing systems.
One way to tackle the interconnect bottleneck is to use light rather than wires to communicate between different parts of a microchip. This is no easy task, however, as silicon, the material used to build chips, does not emit light easily, according to Pablo Jarillo-Herrero, an associate professor of physics at MIT.
Now, in a paper published in the journal Nature Nanotechnology, researchers describe a light emitter and detector that can be integrated into silicon CMOS chips. The paper’s first author is MIT postdoc Ya-Qing Bie, who is joined by Jarillo-Herrero and an interdisciplinary team including Dirk Englund, an associate professor of electrical engineering and computer science at MIT.
Read more at the MIT News Office.
Helen Knight | MIT News Office
October 23, 2017
Interdisciplinary materials research holds the key to solving the e2xistential challenges facing humanity, former Sandia National Laboratories executive Julia M. Phillips told the annual MIT Materials Research Laboratory [MRL] Materials Day Symposium on Wednesday, Oct. 11, 2017. “What is both very exciting for us as materials researchers, also a little frustrating, is that the real impact of materials occurs when they turn into something that you actually carry around in your pocket or whatever,” Phillips said.
During the second half of the 20th century, many of the technological advances that we take for granted today, such as laptop computers and smart phones, came from fundamental advances in materials research and the ability to control and make materials, she noted. Phillips, who retired from Sandia National Laboratories as Vice President and Chief Technology Officer, also serves as chair of the MRL External Advisory Board and is a member of the National Science Board.
MRL formed from the merger of the Materials Processing Center and the Center for Materials Science and Engineering, effective Oct. 1, 2017. MRL Director Carl V. Thompson noted in his introductory remarks, the appointment of Associate Professor of Materials Science and Engineering Geoffrey S.D. Beach as co-director of the MRL and principal investigator for the National Science Foundation Materials Research Science and Engineering Center.
Fueled by industrial needs and government-funded research in the post-World War II era, “Materials research was undeniably an early model for interdisciplinary research,” Phillips said. With new tools such as scanning probe microscopes to understand the structure and properties of materials, materials scientists in the last half of the 20th Century created whole new classes of materials and products, ranging from super alloys that enabled larger and more reliable jet engines to strained layer superlattices that underlie modern magnetic recording,7 lasers and infrared detectors.
Future gains will come from the ability to synthesize and control increasingly complex materials, Phillips says, noting progress in areas such as high-temperature superconductors, porous solids like metal organic frameworks, and metamaterials that generate new properties from combining biological materials, organics, ceramics and metals at near molecular scale precision in ways not found in nature. “Somewhere in the fuzzy space between molecules and materials,” Phillips notes, these newer materials have very interesting properties that are still in the process of being fully explored, and they will be exploited in the years to come. “It’s very clear to many people that these also will be transformational as we move forward,” she says.
The materials research approach, which brings together researchers from across different science and engineering fields to solve complex problems, provides a model for solving 21st Century challenges in energy, environment and sustainability; health care and medicine; vulnerability to human and natural threats; and expanding and enhancing human capability and joy. “These are exemplars, but you can see materials written all over this list, and I would posit that any comparable list you might come up with would have materials written all over it,” Phillips said. “In order to address those grand challenges, we really need to be able to treat realistically complex systems that bring together all of these disciplines from the sciences, from engineering, from the social and behavioral sciences, and arguably even from the arts.”
Progress in scientific understanding and computational modeling are accelerating researchers’ ability to predict the structure and properties of new materials before actually making them, Phillips said.
MIT faculty members Antoine Allanore, Polina Anikeeva, A. John Hart, Pablo Jarillo-Herrero, Juejun Hu, and Jennifer Rupp presented research updates on their recent work which spans a range from ultra-thin layered materials for new electronic devices and cellular level probes for the brain and spinal cord to larger scale methods for 3D printing and metals processing.
Merging 2D materials with CMOS
Associate Professor of Physics Pablo Jarillo-Herrero stacks atomically thin, two-dimensional [2D] layers of different materials to discover new properties. Jarillo-Herrero’s lab demonstrated photodetectors, solar cells and the world’s thinnest LED. With materials such as tungsten selenide [WSe2], changing the number of layers also changes their electronic properties. Although graphene itself has no bandgap, closely aligning the lattices of graphene and boron nitride opens a 30-millivolt bandgap in graphene, he said.
“You have full electronic control with gate voltages,” Jarillo-Herrero said. Using bilayer molybdenum ditelluride, which is 10,000 times thinner than a silicon solar cell, he showed in work published in Nature Nanotechnology, a photodetector just 10 nanometers thick can be integrated on a silicon photonic crystal waveguide.
“You can just stack this at the very end of your CMOS [complementary metal oxide semiconductor] processing, and you don’t have to do any extra fabrication, any extra growth, you can just slap it on top,” Jarillo-Herrero explained. “It can be made as thin as 4 nanometers, so it’s still ultra thin, and you have a high degree of control in an ultra thin platform. The whole thing is semitransparent so we can see the light go in and out.” These new devices can be operated at telecommunications wavelengths by tuning the bandgap of the material.
Phase change materials
Juejun (JJ) Hu, the Merton C. Flemings Associate Professor of Materials Science and Engineering, is reducing power consumption, shrinking device size and ramping up processing speed with innovative combinations of materials that alternate between two different solid states, or phases, such as an alloy of germanium, antimony, selenium and tellurium. These materials are the basis for nonvolatile storage, meaning their memory state is preserved even when the power is turned off. Hu collaborated with MIT Professor Jeffrey C. Grossman and former postdoc Huashan Li to identify desirable materials for these alloys from first principles calculations, and graduate materials science and engineering student Yifei Zhang did much of the experimental work.
An earlier generation of devices based on germanium, antimony and tellurium [GST] suffers from losses to light absorption by the material. To overcome this problem, Hu substituted some of the tellurium with a lighter element, selenium, creating a new four-element structure of germanium, antimony, selenium and tellurium [GSST]. “We increase the bandgap to suppress short wavelength absorption, and we actually minimize any carrier mobility to mitigate the free carrier absorption,” he explained. Switching between amorphous and crystalline states can be triggered with a laser pulse or an electrical signal.
Although the structural state switching happens on the order of 100 nanoseconds, figuring out the techniques to accomplish it took a year of work, Hu said. Specifically, he found that using materials that switch between amorphous and crystalline states allows light to be directed over two different paths and reduces power consumption. He coupled this GSST optical phase change material with silicon nitride microresonators and waveguides to show this behavior. These switches based on phase change materials can be connected in a matrix to enable variable light control on a chip. Ultimately, Hu hopes to use this technology to build re-programmable photonic integrated circuits.
New tools for brain exploration
Class of 1942 Associate Professor in Materials Science and Engineering Polina Anikeeva works at the border between synthetic devices and the nervous system. Traditional electronic devices, with hardness like a knife, can trigger a foreign-body response from brain tissue, which typically is as soft as pudding or yogurt. Working with Prof. Yoel Fink and other MIT colleagues, Anikeeva developed soft polymer-based devices to stimulate and record activity of brain and spinal cord tissue borrowing from optical fiber drawing techniques.
An early version of their multi-functional fibers included three key elements: conductive polyethylene carbon composite electrodes to record brain cell activity; a transparent polycarbonate waveguide with cyclic olefin copolymer cladding to deliver light; and microfluidic channels to deliver drugs.
“Using this structure, for the first time, we were able to record, stimulate and pharmacologically modulate neural activity,” Anikeeva said. But the device recorded activity from clusters of neurons, not individual neurons. Anikeeva and her team addressed this problem by integrating graphite into the polyethylene composite electrodes, which increased their conductivity enough to shrink them into a structure that is as thin as a human hair. The device has six electrodes, an optical waveguide and two microfluidic channels.
Yet adding graphite increased the size and hardness of the glassy polycarbonate device, so her group turned to a new process using rubbery, stretchy polymers that they then coated with a conductive metal nanowire mesh. “This mesh of conductive metal nanowires can maintain low impedance even at 100 percent strain, and it maintains its structural integrity without any changes up to 20 percent strain, which is sufficient for us to operate in the spinal cord,” Anikeeva said.
Her students implanted these nanowire-mesh coated fibers in mice, which allowed them to stimulate and record neural activity in the spinal cord. A video showed a mouse moving its hindlimb when an optical signal delivered to the lumbar spinal cord traveled down the sciatic nerve to the gastrocnemius muscle. In these experiments, the device implanted in mice showed no decline in performance a year after surgery, Anikeeva said.
More recently, Anikeeva developed iron oxide-based nanoparticles that heat up in an applied magnetic field, which can trigger a response from neurons in the brain that express ion channels that are sensitive to heat such as capsaicin receptor, the same mechanism that is triggered when we eat hot peppers. Experimenting with mice, Anikeeva injected these tiny particles deep in the brain in a section that is associated with reward. “In our lab, we have started by modeling hysteresis in magnetic nanoparticles, synthesizing a broad range of these nanomaterials by engineering iron oxide with dopants and looking at different sizes and shapes, developing power electronics and a biological tool kit to assess this process,” Anikeeva explained. “In this case, there is no external hardwire, no wires, no implants, nothing is sticking out of the brain… however, they can now perceive magnetic field.” she said. To quantify their results, the researchers measured calcium ion influx into neurons. Work is now focused on shortening the response time to a few thousandths of a second by improving the heat output of the magnetic nanoparticles.
Ceramics for Solid-State Batteries, CO2 Sensors and Memristive Computing
Jennifer L. M. Rupp, the Thomas Lord Assistant Professor of Materials Science and Engineering, presented research showing a solid lithium garnet electrolyte can lead to batteries miniaturized on an integrated circuit chip.
Safety concerns regarding lithium batteries stem from their liquid component, which serves as the electrolyte and presents a risk of catching fire in air. Replacing the liquid electrolyte with a solid one could make batteries safer, Rupp explained. Her research shows that a ceramic material made of garnet, a material that is perhaps more familiar as a gemstone, can effectively pass lithium through a battery cell, but because it is solid, can be very safe for batteries and also have the opportunity to be miniaturized to thin film architectures. This garnet is a four-element compound of lithium, lanthanum, zirconium and oxygen. “The lithium is completely encapsulated; there is no risk of inflammation,” Rupp said.
In published research, Rupp showed that pairing a lithium titanium oxide anode with a ceramic garnet electrolyte and blurring the interface between the two materials allowed much faster battery charging time for large-scale cells. Lessons learned from applying these garnet materials pointed also to a new use for carbon dioxide sensing. “We can reconfigure the electrodes to have one electrode which simply goes as a reference, and another which undergoes a chemical reaction with carbon dioxide, and we use a tracker potential to track the effective change of carbon dioxide concentration in the environment based on bulk processing,” she explained. Rupp is also developing strained multi-layer materials to improve storage for memristive memory and computing elements.
Frontier for metals at high temperature
Associate Professor of Metallurgy Antoine Allanore pointed out that from 1980 to 2010, the world almost doubled its consumption of materials, with the fastest growth in metals and minerals. Such demand is due to the formidable low cost and high productivity of materials processing. The majority of such processes involve at some stage a high temperature operation and often the molten state of matter. Developing the science and engineering of the molten state brings huge opportunities, for example heat management in high-temperature processes such as metals extraction and glass making.
Steelmaking, for example, is already a highly efficient manufacturing process, turning out rebar, coil or wires of steel at a cost less than 32 cents per kilogram [about 15 cents per pound]. “Productivity is actually the key criteria to make materials processing successful and matter at the scale of the challenge of adding 2 billion people in the next 20 years,” he said.
Allanore’s group demonstrated that tin sulfide at high temperature, about 1,130 degrees Celsius [2,066 Fahrenheit], is an effective thermoelectric generator. “We have indications that the theoretical figure of merit for some sulfides, can be up to 1 at 1,130 [degrees Celsius]. For molten copper sulfide for example, we have estimates of the thermal conductivity, the melting point, and we have a cost that is a little bit high in my opinion, but that’s the nature of the research,” Allanore said. When his group looked at existing data, they found that for many molten compounds of sulfur and a metal, such as tin, lead or nickel, the thermoelectric figure of merit, as well as the compositional phases, had never been quantified, opening a frontier for new materials science research at high temperature. “It’s actually very difficult to know what are the true properties of the liquid,” Allanore said. “I need to know if that material will have semiconductivity. I need to know if it’s going to be denser or lighter than another liquid. … We don’t actually have computational methods to predict such property for liquids at high temperature.”
To address the problem, Allanore studied the relation in high-temperature melts between transport properties, including electrical conductivity and Seebeck coefficients, and a thermodynamic property called entropy. “We’ve put together a theoretical model that connects the transport property, like thermal power, and the thermodynamic property like entropy. This is important because it works for semiconductors, it works for metallic materials and more importantly it allows to find out regions of immiscibility in liquids,” Allanore said. Immiscibility means a material in the given condition will separate into two phases that do not mix together and remain separate.
Allanore has also developed a new method for observing molten compounds such as alumina, using a floating zone furnace, which is a transparent quartz tube located at the focal distance of four lamps. “If we can do that with oxides, we would really like to do that with sulfides,” he explained, showing a picture of molten tin sulfide sitting on a graphite plate in the floating zone furnace. The wide range of temperatures and properties of molten materials, “the ultimate state of condensed matter”, allows for better heat management, higher processing temperatures and electricity harvesting or electrical control of heat flow, he said.
3D printing a new manufacturing model
Traditional manufacturing requires economies of scale, in particular, large production volumes because of the fixed costs necessary to set up the production process, but 3D printing and other additive manufacturing technologies offer an alternative of high-performance, customizable products and devices, Associate Professor of Mechanical Engineering A. John Hart said.
Additive manufacturing is already a $6 billion a year business with reach from Hollywood special effects to high-tech jet engine nozzles. “Additive manufacturing already enables a diverse collection of materials, applications, and related processes – including by extrusion of plastics, melting metals, using lasers, and by coordinated chemical reactions that essentially are done with point wise control,” Hart explained.
“We can think of accessing new spaces in terms of the value of the products we create using additive manufacturing, also generally known as 3D printing. 3D printing is reshaping the axes by which we judge the economic viability of a manufacturing process, and allowing us to access new value spaces. For instance, we can think not only about production volume, but think about advantages in complexity of geometries, and advantages by customization of products to specific markets or even individuals. In these ways, 3D printing is influencing the entire product life cycle,” Hart said.
For instance, Hart’s group studied existing 3D printers to discover how to speed up the process from about 60 minutes to just 5 to 10 minutes to print a handheld mechanical part such as a gear. Former graduate student Jamison Go [SM, 2015] led this work, Hart said, building a desktop 3D printer about the size of a small microwave oven. The system features a control system for the printhead that moves the motors to the corner; an extrusion mechanism that drives the feedstock polymer filament like a screw; and a laser that penetrates and melts the polymer.
“By combining the fast motion control, the high heat transfer, and the high force, we can overcome the limits of the existing system,” Hart explained. The new design is three to 10 times faster in build rate than existing machines. “These kinds of steps forward can also change how we think about producing objects. If you can make something fast, you can think about how you might, or how others might, work differently,” he said. He mentioned, for instance, physicians who may need to 3D print a part for an emergency medical operation, or a repair technician who could use a 3D printer rather than hold inventory of many spare parts.
Hart’s group is currently working in collaboration with Oak Ridge National Lab on algorithms for optimization of 3D printing toolpaths, and adapting his innovations to large-scale 3d printers. “We can think about upscaling these principles to high productivity systems that are not only printing small things but printing big things,” Hart said. Hart has also worked with 3D printing of cellulose, which can be used for customization of consumer products and antimicrobial devices, and is the world’s most abundant natural polymer. He co-founded the company Desktop Metal with three other MIT faculty members and Ric Fulop SL ’06, who serves as Desktop Metal’s CEO. “The company is only two years old and will soon ship its first product which enables an entirely new approach to metal 3D printing,” Hart said.
– Denis Paiste, MIT Materials Research Laboratory
October 30, 2017
Coming up in November Newsletter: Materials Day Panel Discussion and Poster Session coverage